By R. Přibil, R. Belcher, H. Freiser
Analytical purposes of EDTA and similar Compounds examines the analytical purposes of ethylenediaminetetra-acetic acid (EDTA) and similar compounds. This publication additionally considers the “passive” position of those components, that's, their screening (masking) houses, which enormously enhance the selectivity of the reactions in universal use.
This textual content includes six chapters prepared into sections. the 1st half bargains with the makes use of of EDTA and its derivatives in a few fields of chemical research. After offering an summary of the historical past at the back of the improvement of EDTA as an analytical reagent, this e-book discusses to the character of equilibria of complexes and the tools utilized in their research. the following bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions by way of natural reagents. The bankruptcy on colorimetry features a part on “colored complexing agents,” that are used additionally in colorimetric determinations of a few parts. this article concludes by way of comparing using EDTA as a protecting agent in colorimetry.
This e-book could be of curiosity to scholars and practitioners operating in analytical chemistry and similar disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.
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Extra resources for Analytical Applications of EDTA and Related Compounds
I2H2O, Co[Co(HY)Br]2 . IOH2O, Ba[Co(HY)Br]2 . 5H2O, N(CH3)4Co(HY)Br. I4H2O, a n d the dihydrate of the analogous piperidine salt. These salts are relatively unstable a n d easily release the bromide ion, expeciaily on heating. Oxidation of the Co complex in a n alkahne nitrite solution gives the brownish-red K [ C o ( H Y ) N 0 2 ] or N a [ C o ( H Y ) N 0 2 ] · H2O. These complexes are more stable than those containing the bromide ion as the second ligand. 3. Methods of studying the physicochemical properties of EDTA complexes (a) Determination of the stability constant from the titration curve of the acid  The titration curve of E D T A shows three buffering ranges (Fig.
Am. Chem. Soc. 7 4 , 5 0 5 7 ( 1 9 5 2 ) . 3 9 . , COURTNEY, R . C . and MARTELL, A. , / . Am. Chem. Soc. 7 5 , 2 1 8 5 ( 1 9 5 3 ) . 4 0 . TOREN, P . E. and KOLTHOFF, I . , / . Am, Chem. Soc. 7 7 , 2 0 6 1 ( 1 9 5 5 ) . 4 1 . Brit. Patent 4 9 6 , 7 8 1 . 4 2 . U . S . Patent 2 , 4 0 7 , 6 4 5 . 4 3 . U . S . Patent 2 , 1 0 3 , 5 0 5 . 4 4 . SCHWARZENBACH, G . and ACKERMANN, H . , Hel^. chim. acta 3 0 , 1 7 9 9 ( 1 9 4 7 ) . 4 5 . CHAPMAN, D . , / . Chem. Soc. 1 9 5 5 , 1 7 6 6 . 4 6 . PECSOK, R .
Czech. Chem. Comm. 7 , 1 9 8 ( 1 9 3 5 ) . 3 4 . STACKELBERG, M . V. and FREYHOLD, H . , Z . Elektrochem. 4 6 , 1 2 0 (1940). 3 5 . L i N G A N E , J . , Chem. Rev. 29, 1 ( 1 9 4 1 ) . 3 6 . SCHWARZENBACH, G . , K A M P r r s c H , E. and Snen^ER, R . , Helv. chim. acta 2 9 , 3 6 4 ( 1 9 4 6 ) . 3 7 . SCHWARZENBACH, G . , KAMPFTSCH, E . and STED^ÍER, R . , Helv. chim. acta 2 8 , 1 1 3 3 ( 1 9 4 5 ) . 3 8 . , COURTNEY, R . C . and MARTELL, A . , / . Am. Chem. Soc. 7 4 , 5 0 5 7 ( 1 9 5 2 ) . 3 9 .
Analytical Applications of EDTA and Related Compounds by R. Přibil, R. Belcher, H. Freiser