Download e-book for iPad: Asymmetric Reactions and Processes in Chemistry by Ernest L. Eliel

By Ernest L. Eliel

ISBN-10: 0841207178

ISBN-13: 9780841207172

ISBN-10: 0841208786

ISBN-13: 9780841208780

content material: methods for uneven synthesis as directed towards average items / Barry M. Trost --
artificial keep watch over resulting in ordinary items / Teruaki Mukaiyama --
uneven synthesis of chiral tertiary alcohols in excessive enantiomeric extra / Ernest L. Eliel, Jorma okay. Koskimies, Bruno Lohri, W. Jack Frazee, Susan Morris-Natschke, Joseph E. Lynch, and Kenso Soai --
Acyclic stereoselection through the aldol condensation / Clayton H. Heathcock --
uneven carbon-carbon bond forming reactions through chiral chelated intermediates : diastereoselective uneven synthesis of 1,2-disubstituted cycloalkanecarboxaldehydes / Kenji Koga --
uneven carbon-carbon bond forming reactions through chiral oxazolines / Albert I. Meyers --
hugely selective synthesis with novel steel reagents / Hitosi Nozaki, Tamejiro Hiyama, Koichiro Oshima, and Kazuhiko Takai --
Novel methods to the uneven synthesis of peptides / Iwao Ojima --
uneven carbon-carbon bond formation utilizing enantiomerically natural vinylic sulfoxides / Gary H. Posner, John P. Mallamo, Kyo Miura, and Martin Hulce --
uneven reactions : a problem to the commercial chemist / Gabriel Saucy and Noal Cohen --
Stereochemistry of heterogeneous uneven catalytic hydrogenation / Kaoru Harada --
uneven Grignard cross-coupling catalyzed via chiral phosphine-nickel and phosphine-palladium complexes / Tamio Hayashi --
Rhodium(I) catalyzed enantioselective hydrogen migration of prochiral allylamines / ok. Tani, T. Yamagata, S. Otsuka, S. Akutagawa, H. Kumobayashi, T. Taketomi, H. Takaya, A. Miyashita, and R. Noyori --
software of immobilized enzymes for uneven reactions / Ichiro Chibata --
uneven synthesis utilizing cofactor-requiring enzymes / George M. Whitesides, Chi-Huey Wong, and Alfred Pollak --
Mechanistic concerns of biomimetic uneven discounts / Atsuyoshi Ohno --
Stereochemistry of one-carbon move reactions / Heinz G. Floss --
an invaluable and comfortably obtainable chiral desk bound section for the liquid chromatographic separation of enantiomers / William H. Pirkle, John M. Finn, Bruce C. abate, James Schreiner, and James R. Pribish --
New uneven reactions utilizing (S)-2-aminomethylpyrrolidine derivatives / Masatoshi Asami --
Liquid chromatographic solution of enantiomeric [alpha]-amino acid derivatives making use of a chiral diamide section / Shoji Hara, Akira Dobashi, and Masakatzu Eguchi --
uneven relief with chiral NADH version compounds / Yuzo Inouye --
uneven hydrogenation of cyclic dipeptides containing [alpha], [beta]-dehydroamino acid residues and next guidance of optically natural [alpha]-amino acids / Nobuo Izumiya.

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ACS Symposium Series; American Chemical Society: Washington, DC, 1982. ch004 molecule and the above mentioned quote from the master o f organic s y n t h e s i s which planted the seed o f the p r o j e c t which i s discussed i n t h i s a r t i c l e . In c a s t i n g about f o r a method which might be used to a t t a c k the s y n t h e t i c problem posed by erythromycin, I came across a statement by another master — o f the f i e l d o f b i o s y n ­ thesis. W. C o r n f o r t h wrote: "Nature, i t seems, i s an organic chemist having some p r e d i l e c t i o n f o r the a l d o l and r e l a t e d conden­ s a t i o n s .

Asami, M. Chem. Lett. 1978, 1253. ; Asami, M. ibid. 1979, 705. ; Mukaiyama, T. ibid. 1979, 1027. ; Mukaiyama, T. ibid. 1980, 1223. ; Mukaiyama, T. ibid. 1980, 455. ; Kobayashi, S. ibid. 1978, 219. ; Mukaiyama, T. ibid. 1978, 491. ; Suzuki, K. J. Am. Chem. Soc. 1979, 101, 1455. ; Mukaiyama, T. Chem. Lett. 1978, 601. ; Sato, T. ibid. 1979, 447. ; Mukaiyama, T. Bull. Chem. Soc. Jpn. 1979, 52, 3371. ; Suzuki, K. Chem. Lett. 1980, 255. ; Suzuki, K. ibid. 1981, 165. : Osaki, M. ibid. 1977, 1165. ; Fujimoto, K.

3) The c h i r a l adjuvant i t s e l f must be r e c o v e r a b l e i n good y i e l d and without l o s s o f enantiomeric p u r i t y . 4) The c h i r a l adjuvant should be r e a d i l y (cheaply) a v a i l a b l e i n e n a n t i o m e r i c a l l y pure form. In a d d i t i o n , o f course, the s y n t h e s i s must proceed i n acceptable o v e r a l l chemical y i e l d . Statement 1) i s q u a l i t a t i v e and i t s t r a n s l a t i o n i n t o q u a n t i t a t i v e terms i s a matter o f t a s t e .

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Asymmetric Reactions and Processes in Chemistry by Ernest L. Eliel

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